This work was aimed to improve the carbon black from waste tires for printing ink using coupling agent to disperse carbon black particle for making an oil-based offset ink. This experiment used 2 coupling agent these were silane coupling and derivative fatty acid and used to produce offset inks for the 7 formulas. Formula 1 Commercail carbon blackFormula 2 carbon black was not washed by Nitric acid formula 3 carbon black was not washed by Nitric acid and was added silane coupling agent formula 4 carbon black was not washed by Nitric acid and was added fatty acid modified emulsifier formula 5 carbon black was washed by nitric acid formula 6 carbon black was washed by nitric acid and was added silane coupling formula 7 carbon black was washed by nitric acid and was added fatty acid modified emulsifier. Bring all 6 formulas to test property to compare with offset ink commercial. First find the smallest particle of carbon black for 90 minutes. It was found that formula 4 took 20 minutes to make particles 12 micron and it is smalles particle of all. Then measured ink flow by Spread-O-Meter and measured diameter after 1 minute. It was found that formula 3 and 3 were 77 mm. and approximate commercial ink. Then measured tack of ink with Ink-O-Meter it was found that formula 2 3 4 6 and 7 were 2.4 and formula 5 was 2. Then measured viscosity and yield value of ink by Lary viscometer. It was found that formula 2 had 77 poise of ink viscosity and 670 dyne.s/cm2 of ink yield value that was approximate commercial ink. Finally measured Emulsification capacity (%) by Kershaw Water Pick up Tester. It was found that formula 6 had 74% and it was approximate commercial ink.