Hydrogen sulfide (H25 cheap materials activated carbon scraped iron sand cement and rice husks applied to the small scale biogas production at 30 ppm within 6 hours. The filter materials with highest to lowest H48.18 percent respectively. In the medium scale biogas production (20 L) at 30 ppm. Scraped iron and sand mixed with activated carbon filter had the best H(200 L) production of the biogas fermentation (30 ppm biogas product) sand mixed with activated carbon filter at the ratio 60:40 displayed the best performances in removing H2(3 day). It is the most environmental friendliness as well as cost-effective filter for biogas fermentation at scale up sizes at least 20 L. S) is found to be one major serious contaminant to biogas production system. In this research the team aimed to develop a high efficient filter for removing H2S from the biogas reaction. From all 2S absorptivity were activated carbon sand scraped iron and rice husks those accounted for 88.02 76.06 55 50 and 2S absorptivity (100 percent) and sand showed its H2S removal efficiency lower at 65 percent respectively. In larger scale S after incubated for 4.5 hours while scraped iron filter as well as activated carbon filter functioned in H2S removal longer time (2 and 3 days respectively). In order to be able to practically apply for continuous filtering H2S from the continuous biogas production sand mixed with activated carbon filter exhibited long last filtration

A promising composite of zinc ferrite (ZnFe2O4) and bioactive hydroxyapatite (Ca10(PO4)6(OH)2 ;HAp) has expected to potential for future bone reinforcing formation. In present study zinc ferrite and hydroxyapatite composite was prepared by solid state reaction route for easier control of structural and magnetic characteristics and with low cost. Hydroxyapatite powder was synthesized by precipitation method from chicken eggshell. Mixed powders with varying ZnFe2O4/HAp weight ratios from 2-10 wt% were milled together and uniaxially pressed and then sintered at 1200 oC for 3 hours. The XRD results showing no other phases of composite with only HAp and ZnFe2O4 phases were identified indicating high stability of HAp property. Phase fractions of ZnFe2O4 were found to increase from 10.8 to 18.73 wt% with increasing content of ZnFe2O4. FT-IR results of ZnFe2O4/HAp composite were only revealed vibration bands of standard HAp phase. This may due to the overlapping of the ZnFe2O4 vibrational bands with HAp bands. However their intense variations observed in HAp vibrational bands indicated the interaction between ZnFe2O4 and HAp. The surface morphology of these ZnFe2O4/HAp composite exhibited primary grain in nano scale with enhanced pore structure and Interconnectivity when ZnFe2O4 weight ratios increased; indicating high surface area for cell attachment and better good cell growth and differentiation. The higher saturation magnetization as well as higher super paramagnetic behavior could be easily altered by increasing ZnFe2O4 content in the composite.

Research this project invents for design and build the water turbine produce the electricity by set up the equipment produces the electric current from water energy flows from the nature which be new choice for Thailand in using energy pays back. then born the idea in energy water lead flows in the tide comes to use is born the advantage The water turbine has produced the electricity that does designing and establish to compose 3 part importance be the part of water buoy water turbine part is the pin wheel that is made of the iron each have a draught 90 centimeter group part carries round which compose the gearwheel yes carry round and a transmitting belt carry round . From pin wheel test produces the electric current that establishes to induce float in a river already record seek feeling numb fire efficiency reaches to open 12 DC good and use inverter to 220 v. AC

The objective of this research is to propose a new way to fabricate a composite material for future bone replacement development via growing apatite crystal on silk fibroin fiber. Apatite crystallization on silk fibroin fiber was prepared by precipitation reaction between Ca(NO3)2 solution and (NH4)2HPO4 solution adjusted pH by NH4OH solution. In this work Effect of solution concentration and initial pH values was investigated on apatite crystals. Chicken eggshells were used as calcium source by heating sufficiently powdered eggshells at 1300 °C for 4 h to acquire CaO powders made Ca(NO3)2 solution by dissolving in 65% HNO3 solution. Prepared Ca(NO3)2 solutions were adjusted concentration as 3 levels and were adjusted different pH values of 7 8 and 9 respectively. For processing of apatite crystallization silk fibroin fibers were immersed in Ca(NO3)2 solutions for 30 min. After that (NH4)2HPO4 solutions were added in silk fibroin fibers immersed in Ca(NO3)2 solutions. Reaction time was fixed about 1 min before cleaning to remove impurity precipitates on surface of silk fibroin fiber. Finally apatite crystallization on silk fibroin fibers occurred. The obtained result can conclude morphologies of apatite crystals on silk fibroin fibers was sheets sphere and flower. Solution concentrations and initial pH values directly influenced on Ca/P ratio of obtained apatite crystals by Ca/P ratio increases as increased solution concentrations or increased pH values. Finally research silk fibroin fibers were woven as two patterns of plain weave and twill weave and they were investigated Young’s modulus and tensile strength. The result indicates that Young’s modulus of silk fibroin fiber sheets woven as twill weave and as plain weave were about 616 MPa and 425 Mpa and tensile strengths of them weave were about 40 Mpa and 72 Mpa respectively. The optimum condition of growing apatite crystals on silk fibroin fibers was sample of CP19. Design of silk fibroin fiber with plain weave was an optimum pattern for future biomedical applicaions.

The cobalt catalysts (cobalt content by weight: 7% 10% and 15%) and cobalt-nickel bimetallic catalysts (cobalt-nickel content by weight: 3.5%-3.5% 5%-5% and 7%-7%) were studied in dry reforming of methane for hydrogen and syngas production. All catalysts were synthesized by the wetness impregnation method. The dry reforming of methane was carried out at 700oC atmosphere pressure using a mixture; CH4 and CO2 in ratio 1:1. The result showed that the good activity and stability depend on metal content in catalysts and the combined 2 metals as bimetallic catalysts. The optimum amounts of catalysts are 10wt% Co for mono-metallic catalysts 75%CH4 and 75%CO2 conversion and 7wt% Ni-7wt% Co for bimetallic catalysts 87%CH4 and 89%CO2 conversion.