จำนวน Repository ( 22 )

การบำบัดน้ำสีย้อมผ้าโดยกระบวนการแอดวานซ์ออกซิเดชันด้วยโอโซน ร่วมกับสารไฮโดรเจนเปอร์ออกไซด์
การบำบัดน้ำสีย้อมผ้าโดยกระบวนการแอดวานซ์ออกซิเดชันด้วยโอโซน ร่วมกับสารไฮโดรเจนเปอร์ออกไซด์

This research is a study on treatment of Water Dyes from textile dyeing industry by Advance oxidation process with Ozone and hydrogen peroxide (H2O2). In this study Ozone generators with a capacity of 1.0 - 3.0 mg/ hr. were used to study the appropriate factors for treatment with adjusting wastewater conditions (pH 3 pH 7 and pH 11) Ozone exposure distance 120 minute the initial COD concentration is 250 - 1000 mg/l. and adding hydrogen peroxide at 4 8 and 12 ml/l. For the study found that above mentioned factors have an effect on the efficacy of color and COD treatment which the experiment at pH 11 used to Ozone treatment and added 4 ml/l. of H2O2. It makes the highest COD treatment efficiency when compared to pH 3 pH 7 and added more H2O2. it doesn’t affect to the higher of treatment efficiency. In addition it was found that higher initial COD concentration decreased treatment efficiency which the experimental ability for COD treatment has highest value was 46 percent and the COD concentration was 250 ml/l In order that when COD concentration in synthetic color water was increased to 500 ml/l and 1000 ml/l. it was found that the COD efficiency decreased to 31% and 40% respectively. For the treatment of Water Dyes from textile dyeing industry by oxidation process with Ozone together with hydrogen peroxide (H2O2) at pH 7 will has the highest of treatment efficiency. However the consideration of suitability for pH configuration used to treat both color and COD should choose pH 11 because it can treat both color and COD that makes the waste water quality meet the standards required by law. In addition if we consider the effectiveness of turbidity and BOD found that the decrease of dirtiness tends to be in the same direction with COD both 2 parameters.

2565
การบำบัดน้ำเสียจากสีย้อมผ้าด้วยกระบวนการโอโซนเนชัน โดยใช้ตัวกลางพลาสติก เคลือบผิวไทเทเนียมไดออกไซด์ชนิดรูไทล์เป็นตัวเร่งปฏิกิริยา
การบำบัดน้ำเสียจากสีย้อมผ้าด้วยกระบวนการโอโซนเนชัน โดยใช้ตัวกลางพลาสติก เคลือบผิวไทเทเนียมไดออกไซด์ชนิดรูไทล์เป็นตัวเร่งปฏิกิริยา

This research is to study the efficiency of treating wastewater from dyeing fabric by the ozonation process. By using rutile TiO2 coated plastic media to catalyze. Which uses O3 generators with a capacity of 2.62 - 3.10 g/hr. By studying the factors that affect the treatment efficiency of COD and color such as the pH of the water used in the treatment at pH 3 pH 7 and pH 11 the initial COD concentration of 100% 50% and 25% which have values in the range of 100 -320 mg/L. O3 exposure time 120 min. From the study it is found that the efficiency of reducing the impurities in wastewater by the ozonation process in the pH 11 state the COD concentration at 50% can reduce the COD. And the maximum color is at 33.3% and 90% from the 550 ADMI color intensity with a COD of 180 mg/L. For the study of the efficiency of reducing the impurities of wastewater by ozonation process together with 2 g. of TiO2/1 L. of wastewater in the condition of pH 11 concentration COD Beginning at 100% with the ability to reduce COD values And the maximum color is at 40% and 80% of the 270 ADMI color intensity with a COD of 190 mg/L. The amount of O3 suitable for treatment has an average value of 0.0374 g/min./10.5 L. of wastewater. The duration of O3 exposure in both processes has a similar approach to the efficiency of COD and color treatment when increasing the duration of O3 exposure.

2565
การดูดซับสีย้อมเมทิลีนบลูบนถ่านกัมมันต์ที่เตรียมจากกากน้ำตาลโดยวิธีการกระตุ้นด้วยสารเคมีและไมโครเวฟ
การดูดซับสีย้อมเมทิลีนบลูบนถ่านกัมมันต์ที่เตรียมจากกากน้ำตาลโดยวิธีการกระตุ้นด้วยสารเคมีและไมโครเวฟ

This research aims to produce activated carbon from molasses via a chemical activation process with potassium hydroxide (KOH) and a microwave heating process which consumes less energy and provides more rapid and uniform heat distribution than a conventional heating. The obtained activated carbon was then characterized with BET SEM and FTIR. It exhibited a large specific surface area of 1631 m2/g and a total pore volume of 1.124 cm3/g consisting of mesopore and micropore. In addition the active functional groups were also found on the surface of the activated carbon. Thus it was brought for the adsorption test with methylene blue. It was found that the adsorption capacity of the activated carbon increased with time and reached the equilibrium within 8 hours. The adsorption data of the activated carbon were corresponded to Langmuir isotherm with the highest adsorption capacity of 370.37 mg/g. The adsorption kinetic of the activated carbon exhibited pseudo-second order reaction suggesting to the chemisorption phenomenon. From the thermodynamic study it revealed that the adsorption process were endothermic and spontaneous reactions.

2565
การกำจัดสีย้อมผ้าด้วยถ่านกัมมันต์จากเมล็ดสละพันธุ์สุมาลีที่กระตุ้น ด้วยสารละลายโพแทสเซียมไฮดรอกไซด์
การกำจัดสีย้อมผ้าด้วยถ่านกัมมันต์จากเมล็ดสละพันธุ์สุมาลีที่กระตุ้น ด้วยสารละลายโพแทสเซียมไฮดรอกไซด์

Dyes contaminated in wastewater that negatively affecting the environment and human health. The objectives of this study to prepare activated carbon from Salacca zalacca (Sumalee) seeds activated by 36 mmol/g KOH dye solution and activated carbon ratio 20:32 ml/g for dye removal. The influents of dye removal from wastewater by Salacca zalacca (Sumalee) seeds activated carbon were investigated as initial dye concentration activated carbon and dye solution ratio and contraction time. The moisture content the iodine number the methylene blue index and the functional groups by FTIR technique of the Salacca zalacca (Sumalee) activated carbon were characterized and the kinetics adsorption were also analyzed. The results showed that the activated carbon was the microporous material the highest dye removal from wastewater was 7.50 ± 0.25 mg/g the equilibrium time was 150 min with the activated carbon to dye solution ratio of 1:500 g/ml for 200 mg/l initial concentration. The kinetics of the adsorption process can be described by a pseudo-second order model (R2 = 0.9999). When increasing the initial concentration of dyes the adsorption efficiency was increased. The amount of activated carbon increased resulting in lower adsorption efficiency and the equilibrium time was longer

2564
การดูดซับสีย้อมเมทิลีนบลูของถ่านเปลือกส้มโอที่เตรียมจาการเผาแบบเตาลาน
การดูดซับสีย้อมเมทิลีนบลูของถ่านเปลือกส้มโอที่เตรียมจาการเผาแบบเตาลาน

The pomelo peels charcoal was successfully prepared by traditional charcoal burning and its adsorption of methylene blue was investigated. The influences of methylene blue adsorption including contact time and methylene blue initial concentration were studied at room temperature. The adsorption rate initially increased rapidly until 24 h and 600 mg/L of methylene blue initial concentration. The further increase in contact time and methylene blue initial concentration did not significantly increase the adsorption due to it reached equilibrium. Kinetic of adsorption were investigated that the pseudo-second order model best described adsorption kinetic data. The adsorption isotherms were evaluated and the data correlated with Langmuir adsorption model with the maximum adsorption capacity was found to be 166.67 mg/g. The adsorption of pomelo peel charcoal was studied comparing to other adsorbents at the same experimental conditions. The results showed higher adsorption of pomelo peel charcoal than dried pomelo peel longan wood charcoal coconut shell charcoal litchi wood charcoal and tamarind wood charcoal respectively.

2563