จำนวน Repository ( 6 )
การสังเคราะห์แก้วเซรามิกชนิดไฮดรอกซีอะพาไทต์ที่มีการเติมเซอร์โคเนียมสำหรับการประยุกต์ใช้ในทางทันตกรรม
The aim of this work was to fabrication of Hydroxyapatite Glass-ceramic by adding ZrO2 for Dental Application. The glasses were prepared by conventional melting of the coprecipitation derived starting products and heat treated at different temperatures. The structure mechanical properties and microstructure of the samples were characterized by X-ray diffraction Vicker hardness energy dispersive X-ray analysis (EDXA) and scanning electron microscopy. The data showed that the samples with condition Li1-1450 and heated treatment at 830 C having high strength and proper crystallinity showed good translucency which comparable with that of the sample from factory. XRD analysis revealed XRD analysis revealed that the peak corresponds to the crystallization of Li2SiO3 SiO2or Li6SiO8which are important phases have effect to increasing the mechanical properties of samples.
การปรับปรุงสมบัติทางชีวภาพและสมบัติการละลายของแก้วและแก้วเซรามิกชีวภาพ ในระบบโซเดียมแคลเซียมฟอสเฟตเพื่อนาไปประยุกต์เป็นกระดูกเทียม
This research then has two main objectives. The first objective is to fabrication of bioactive glass ceramics containing BaFe12O19 (BF) crystals has been carried out for the application in hyperthermia treatment. The BaFe12O19 powder was firstly prepared and subsequently mixed with the non-silicate P2O5-CaO-Na2O bioactive glass with various BF concentrations. After that the glass ceramics were produced via a sintering method at 600◦C and their crystal phases were examined by XRD and in vitro test was carried out by soaking in simulated body fluid. Remanence and saturation magnetization and coercivity were deduced from magnetic measurement. It was found that the samples exhibited magnetic behavior which is similar to hard magnetic materials. Our second objective is the effects of sintering temperatures on the physical and bioactivity of SrFe12O19 (SF)-P2O5-CaO-Na2O bioglass ceramics were investigated. XRD results confirmed the existence of the strontium ferrite and calcium phosphate phases. SEM images showed that grain size and hardness were related to density and liquid phase present in the samples. A maximum coercivity value of 3138 Oe was obtained for the bioglass ceramic sintered at 600 ºC. The remanence (Mr) and saturation magnetization (Ms) of the bioglass ceramic sintered at 500 ºC possess the maximum value of 6.35 and 10.64 emu/g respectively. Moreover the apatite was formed on the surface layers of the bioglass ceramics confirming their biocompatibility
การปรับปรุงสมบัติทางชีวภาพและสมบัติการละลายของแก้วและแก้วเซรามิกชีวภาพ ในระบบโซเดียมแคลเซียมฟอสเฟตเพื่อนาไปประยุกต์เป็นกระดูกเทียม
This research then has two main objectives. The first objective is to fabrication of bioactive glass ceramics containing BaFe12O19 (BF) crystals has been carried out for the application in hyperthermia treatment. The BaFe12O19 powder was firstly prepared and subsequently mixed with the non-silicate P2O5-CaO-Na2O bioactive glass with various BF concentrations. After that the glass ceramics were produced via a sintering method at 600◦C and their crystal phases were examined by XRD and in vitro test was carried out by soaking in simulated body fluid. Remanence and saturation magnetization and coercivity were deduced from magnetic measurement. It was found that the samples exhibited magnetic behavior which is similar to hard magnetic materials. Our second objective is the effects of sintering temperatures on the physical and bioactivity of SrFe12O19 (SF)-P2O5-CaO-Na2O bioglass ceramics were investigated. XRD results confirmed the existence of the strontium ferrite and calcium phosphate phases. SEM images showed that grain size and hardness were related to density and liquid phase present in the samples. A maximum coercivity value of 3138 Oe was obtained for the bioglass ceramic sintered at 600 ºC. The remanence (Mr) and saturation magnetization (Ms) of the bioglass ceramic sintered at 500 ºC possess the maximum value of 6.35 and 10.64 emu/g respectively. Moreover the apatite was formed on the surface layers of the bioglass ceramics confirming their biocompatibility
การผลิตแก้วเซรามิกชนิดลิเทียมไดซิลิเกตสำหรับประยุกต์ใช้ทางทันตกรรม
The purpose of this project is analyze to the transparency and mechanical properties of lithium disilicate for dental application. Lithium disilicate glass-ceramic were synthesised by using melting technique in SiO2-Li2O-Al2O3-K2O -P2O5 glass system and heated treatment samples at the crystallization temperature of that glass. The Differential thermal analysis: DTA X-ray diffraction: XRD were used analysis on thermal properties phase formation. Moreoven density Hardness were determined to evaluate the properties at physical and Mechanical respective by the X-ray diffraction showed that the glass-ceramic sample demonstrated the phase of Li2SiO3 Li2Si2O5 and SiO2 . The optimum of glass-ceramic. Sample were on faired with the sample heated 650°c first step and heated at 800°c for second step. That show the highest hardness valve at 755 HV
การศึกษาแก้วเซรามิกชีวภาพที่ประกอบด้วยผลึกเฟอร์โรแมกเนติกระดับนาโนจากระบบที่มีและไม่มีซิลิกาเป็นองค์ประกอบด้วยวิธีอินคอเปอเรชัน
The aim of this work was to study the magnetic properties of magnetic glass-ceramics with composition system SiO2-CaO-Na2O-P2O5-BaO-Fe2O3. The magnetic glass–ceramics were prepared by conventional melting at 1300oC for 2 h of the coprecipitation derived starting products and heat treated at different temperatures. The structure and microstructure of the samples were characterized by X-ray diffraction energy dispersive X-ray analysis (EDXA) and scanning electron microscopy. The magnetic measurement showed that the samples which contained barium ferrite exhibited magnetic behavior which is similar to soft magnetic materials. Finally the samples were soaked in simulated body fluid (SBF) for 14 days. The apatite was found to form on the surface layer of glass-ceramics and it increases with the barium ferrite content was increased.