This research aims to develop the waste heat energy conversion device to generate electricity through a thermoelectric generator (TEG) which is called “CHEU. This device is applied to the LPG cookstove that serves as a waste heat source. The thermoelectric generator with 4 modules in series connection is used to convert heat energy to electricity. The present research shows a modification of the CHEU based on two concepts as follows: (1) re-design the structure for heat transfer improvement and (2) select the high capability of TEG to support a high temperature from a heat source as a result of (1). In this study the modified CHEU is called “MCHEU”. A heat-load condition is set as the gas pressure of LPG which varies in a range of 0.1 - 0.6 kg/cm2 and the throttle valve is fixed approximately at 40% of a fully opened throttle while the air entrainment is fully opened throttle. Also the water-cooling system is used for heat dissipation. Base on the performance evaluation of MCHEU the interesting results are drawn as follows: 1) the maximum temperature difference is on an average value of 278.5oC at a maximum heat load condition while a maximum voltage current and power are on an average value of 18.83 V 5.67 A and 107 W respectively. 2) The temperature difference of MCHEU is higher than that of CHEU with an average value of 50%. 3) The output power obtained by MCHEU is higher than that of CHEU with an average value of 52% and takes less time about 40% for fully charging a battery (12V 7.5Ah). Nevertheless MCHEU usage does not affect the thermal efficiency of a cookstove. 4) The efficiency of an energy conversion obtained by MCHEU is 20% which is higher than that of CHEU about 2%.